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51.
Ying Lin Teng‐Ling Ye Yu Chen Dong‐Ge Ma Zhi‐Kuan Chen Yan‐Feng Dai Yong‐Xi Li 《Journal of polymer science. Part A, Polymer chemistry》2010,48(24):5930-5937
A new bipolar conjugated polyfluorene copolymer with triphenylamine and cyanophenylfluorene as side chains, poly{[9,9‐di(triphenylamine)fluorene]‐[9,9‐dihexyl‐fluorene]‐[2,7‐bis(4′‐cyanophenyl)‐9,9′‐spirobifluorene]} ( PTHCF ), was synthesized for studying the polymer backbone emission. Its absolute weight‐average molecular weight was determined as 4.85 × 104 by using gel permeation chromatography with a multiangle light scattering detector. In contrast to the electronic absorption spectrum in dilute solution, the absorbance of PTHCF in thin film was slightly blue shifted. By comparison of the solution and thin‐film photoluminescence (PL) spectra, a red shift of Δλ = 8–9 nm was observed in the thin‐film PL spectrum. The HOMO and LUMO energy levels of the resulting polymer were electrochemically estimated as ?5.68 and ?2.80 eV, respectively. Under the electric‐field intensity of 4.8 × 105 V cm?1, the obtained hole and electron mobilities were 2.41 × 10?4 and 1.40 × 10?4 cm2 V?1 s?1, respectively. An electroluminescence device with configuration of ITO/PEDOT:PSS/ PTHCF 70%+PBD30%/CsF/Ca/Al exhibited a deep‐blue emission as a result of excitons formed by the charges migrating along the full‐fluorene main chain. The incorporation of the bipolar side chains into the polymer structure prevented the intermolecular interaction of the fluorene moieties, balance charge injection/transport, and thereby improve the polymer backbone emission. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 相似文献
52.
Qian Yang Yiding Xu Hao Jin Zhihao Shen Xiaofang Chen Dechun Zou Xinghe Fan Qifeng Zhou 《Journal of polymer science. Part A, Polymer chemistry》2010,48(7):1502-1515
Mesogen‐jacketed liquid crystalline polymers (MJLCPs) with both electron‐transport oxadiazole and hole‐transport thiophene in the side chain were reported for their promising electroluminescent property. Monomers of 2,5‐bis{5‐[(4‐alkoxyphenyl)‐1,3,4‐oxadiazole]thiophen‐2‐yl}styrene (M‐Cm, m is the number of the carbons in the alkoxy groups, m = 8,10) were synthesized and confirmed by 1H‐NMR, mass spectrometry, and elemental analysis. The corresponding polymers were successfully obtained and characterized by thermal analysis, optical spectroscopy, cyclic voltammetry, electroluminescent analysis, polarized light microscopy (PLM), and wide‐angle X‐ray diffraction (WAXD). The polymers exhibited high decomposition temperatures reaching 382 °C and high Tg's reaching 184 °C. The absorption spectra indicated that both the monomers and polymers had little aggregation in film than that in solution, and the absorption spectra of the polymers showed an obvious blue‐shift compared with those of the monomers. Both the monomers and the polymers had blue‐green emission, and the photoluminescence spectra of the polymers in film suggested the formation of excimer or exciplex. The polymers showed lower HOMO energy levels and LUMO energy levels than those of the MJLCPs containing oxadiazole unit reported before. Electroluminescence study with the device configuration of ITO/PEDOT/PVK/polymer/TPBI/Ca/Ag showed maximum brightness and current efficiency of 541 cd/m2 and 0.10 cd/A, which proved that the introduction of directly connected electron‐ and hole‐transport units could greatly improve the EL property of side‐chain conjugated polymers. The phase structures of the polymers were confirmed to be smectic A phase through the results of PLM and WAXD. The annealed samples emitted polarized photoluminescence at room temperature, which indicated potential utility for practical applications in display. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 1502–1515, 2010 相似文献
53.
Junpeng Zhao Guangzhao Zhang Stergios Pispas 《Journal of polymer science. Part A, Polymer chemistry》2010,48(11):2320-2328
Thermoresponsive brush copolymers with poly(propylene oxide‐ran‐ethylene oxide) side chains were synthesized via a “grafting from” technique. Poly(p‐hydroxystyrene) was used as the backbone, and the brush copolymers were prepared by random copolymerization of mixtures of oxyalkylene monomers, using metal‐free anionic ring‐opening polymerization, with the phosphazene base (t‐BuP4) being the polymerization promoter. By controlling the monomer feed ratios in the graft copolymerization, two samples with the same side‐chain length and different compositions were prepared, both of which possessed high molecular weights and low molecular weight distributions. The results from light scattering and fluorescence spectroscopy indicated that the brush copolymers in their dilute aqueous solutions were near completely solvated at low temperature and underwent slight intramolecular chain contraction/association and much more profound intermolecular aggregation at different stages of the step‐by‐step heating process. Above 50 °C, very turbid solutions, followed by macrophase separation, were observed for both of the samples, which implied that it was difficult for the brush copolymers to form stable nanoscopic aggregates at high temperature. All these observations were attributed, at least partly, to the distribution of the oxyalkylene monomers along the side chains and the overall brush‐like molecular architecture. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2320–2328, 2010 相似文献
54.
庚烯-1单体单元对胆甾型侧链液晶共聚砜热转变温度的调节 总被引:6,自引:0,他引:6
合成并用红外光谱法、核磁共振法和高效凝胶渗透色谱法表征了胆甾(烷)醇十一碳烯酸酯分别与庚烯 1、二氧化硫进行自由基共聚合得到的一系列不同组成的三元胆甾型侧链液晶共聚砜,用温控式偏振光显微镜观测了产物的液晶性能.结果表明:随庚烯 1单体单元组份含量的增加,该三元共聚砜的液晶相转变温度均降低,采用庚烯 1单体参与共聚的方法可以有效地调节胆甾型侧链液晶共聚砜的热转变温度. 相似文献
55.
用准连续60W的二极管激光列阵侧面泵浦“之”字形Nd:YAG板条激光器,当泵浦功率为45W,脉宽为400μs时,得到3.5mJ的激光输出。用KD*P电光开关调Q,得到18ns(FWHM)、2mJ的脉冲激光输出,用KTP晶体作腔内倍频,得到15ns、0.85mJ的二次谐波激光输出。在腔内无调Q元件且腔长小于5cm时,于近阈值处得到单频绿光输出,而当泵浦功率稍大,腔内有数个纵模振荡时,观察到激光的反相态,并用数值模拟的结果对此作了解释。 相似文献
56.
Jiangang Gao Youyi Sun Jingli Zhou Zhi Zheng Hongwei Chen Wei Su Qijin Zhang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(23):5380-5386
A new synthetic approach to prepare Ag nanoparticles protected side‐chain liquid crystalline (LC) azobenzene polymers was reported. It is based on the reduction of silver ions in presence of a LC polymer polymerized by RAFT. The formation of Ag colloidal nanoparticles was confirmed by TEM and UV analysis. At the same time, according to the results of DSC, XPS, and FTIR spectra, Ag nanoparticles were protected by the side‐chain LC azobenzene polymers through surface attachment interactions between thiol groups and Ag. The out‐plane orientation of side‐chain LC is confirmed by surface‐enhanced Raman spectra analysis and scanning near‐field optical microscope, resulting from the large electromagnetic field arising from the excitation of surface plasmon polariton of Ag nanoparticles. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5380–5386, 2007 相似文献
57.
Severin Eder Manuel Torko Alessia Montalbetti Paride Azzari Laura Nystrm 《Molecules (Basel, Switzerland)》2021,26(11)
The pace of industrialization and rapid population growth in countries such as India entail an increased input of industrial and sanitary organic micropollutants, the so-called emerging contaminants (EC), into the environment. The emission of EC, such as pharmaceuticals, reaching Indian water bodies causes a detrimental effect on aquatic life and ultimately on human health. However, the financial burden of expanding sophisticated water treatment capacities renders complementary, cost-efficient alternatives, such as adsorption, attractive. Here we show the merits of washed and milled pigeon pea husk (PPH) as low-cost adsorbent for the removal of the EC trimethoprim (TMP) and atenolol (ATN) that are among the most detected pharmaceuticals in Indian waters. We found a linear increase in adsorption capacity of PPH for TMP and ATN at concentrations ranging from 10 to 200 μg/L and from 50 to 400 μg/L, respectively, reflecting the concentrations occurring in Indian water bodies. Investigation of adsorption kinetics using the external mass transfer model (EMTM) revealed that film diffusion resistance governed the adsorption process of TMP or ATN onto PPH. Moreover, analysis of the adsorption performance of PPH across an extensive range of pH and temperature illustrated that the highest adsorption loadings achieved concurred with actual conditions of Indian waters. We anticipate our work as starting point towards the development of a feasible adsorbent system aiming at low-cost water treatment. 相似文献
58.
59.
60.
V. V. Filippov 《Mathematical Notes》1997,61(3):340-345
The verification of an appropriately stated equicontinuity condition for a sequence of solution spaces is one of the two key
points in the theory of the Cauchy problem for equations with singular right-hand sides. We obtain a related sufficient condition.
Translated fromMatematicheskie Zametki, Vol. 61, No. 3, pp. 416–423, March, 1997.
Translated by V. E. Nazaikinskii 相似文献